Let entropy S be imagined as a function of T and V, then
dS = (dS / dT )v dT + ( dS / dV )t dV
TdS = T (dS / dT)v dT + T ( dS / dV) t dV
Since T (dS / dT)v = Cv, heat capacity at constant volume, and
( dS / dV ) t = (dp / dT ) v , Maxwell's third equation,
TdS = CvdT + T (dP / dT)v dV
This is known as first TDS Equation,
If S = S (T,p)
dS = (dS / dT)p dT + (dS / dp)t dp
TdS = T (dS / dT)p dT + T( dS /dP)t dp
Since then T ( dS / dT )p = Cp, and (dS /dp)t = -(dV / dT)p
TdS = CpdT - T( dV/ dT)p dp
This is known as the second TdS equation.
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